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212MN- Austenitic Stainless Steel

Steel data sheets

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Valbruna Grade


Steel type

Austenitic Stainless Steel

Description of material

212MN is a Cr- Ni – Mn - N precipitation hardening austenitic stainless steel designed for high strength and hot corrosion resistance at elevated temperature. This grade has a lower Nickel and Nitrogen content than 214MN.


Exhaust valves for gasoline and diesel internal combustion engines where a high temperature strength and corrosion resistance to engine combustion products are needed. It is used for exhaust valves for engines in the majority of cars. Its maximum operating temperature is 750° C. In addition, 212MN has been used in heavy duty intake valves of certain engines.

Melting practices

Argon Oxygen Decarburization

Corrosion resistance

212MN has a good resistance to oxidation and sulfidation at elevated temperatures. When solution treated and aged, this grade warrants an austenitic structure with high hardness and the best creep resistance.

Cold working

212MN has poor ductility in the annealed condition and is difficult to machine due to Mn and N contents. It’s very difficult to machine this grade and only the grinding process should be carried out. In the case of turning, a right choice of tool geometry, feed and cutting fluids should be well evaluated to minimize the strain hardening of the surface avoiding the possibility of stress delayed cracks. Abrasive wheel cutting is suggested instead of band and circular sawing. However, abrasive wheel cutting should be carried out with great care and with very good cooling conditions in order to avoid the overheating of the cross-section of bars. For extrusion bars, warm or hot shearing are suitable and correct processes. For small bars, such as precision ground bars for upsetting, the cold shearing (cropping) is preferred but the structure of 212MN requires a small clearance between the edge of upper and lower tool in order to facilitate the fracture avoiding large burrs heights and shear cracks. It’s important to point out that this grade, as with similar high Mn - N valve grades, the shift in ductile-brittle transition temperature curve is just 30°-50° C above room temperature.


In solid state joining such as Friction Welding, 212MN provides a quality bond line. When friction welded with stems of alloy or martensitic steel, a stress relieving or tempering of valves is mandatory and must be done in order to soften the martensitic structure of HAZ and bond line.

Hot working

212MN is suitable for processing by hot extrusion or by upsetting with electric resistance heating. However, overheating must be always avoided. The choice of hot working temperature and process parameters must always evaluate both the strain rate and the consequent increasing of temperature that is reached after hot deformation. High strain rates and temperatures at top end of the range during the extrusion and forging process, could generate internal bursts of the stem of valves. The same care should be carried out for electrical upsetting process in order to maintain the right geometry of the bulb and to avoid hot cracks and internal shortness of the head valve. In both processes, a low or medium temperature range of hot working is recommended.

Heat treatment

Valves of 212MN should be always solution treated and aged to obtain the best creep resistance and elevated temperature corrosion resistance of exhaust valves.


W.N. 1.4875
UNS S63012
EN X55CrMnNiN20-8
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